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1. 发明授权

US5058647A Tire having decorative applique on sidewall and method for preparing same 失效
标题翻译：具有侧壁装饰贴花的轮胎及其制备方法
公开(公告)号：US5058647A
公开(公告)日：1991-10-22
申请号：US568119
申请日：1990-08-16
申请人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
发明人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
IPC分类号： B29D30/72 , B60C13/04
CPC分类号： B60C13/04 , B29D30/72 , B29D2030/726 , Y10S152/12
摘要： Tires having white sidewalls are very popular in the United States and Canada. Tires having white lettering thereon are also very popular. This invention discloses a process for preparing such tires having decorative appliques thereon. By practicing the process of this invention, tires having better uniformity can be built at lower costs than when standard tire building techniques are utilized. This invention specifically relates to a method of preparing a pneumatic rubber tire having a decorative design on the sidewall thereof which comprises (a) applying the decorative applique to the sidewall of an uncured tire and (b) curing the tire; wherein the decorative applique is comprised of from about 25 weight percent to about 75 weight percent syndiotactic 1,2-polybutadiene having a melting point which is within the range of about 70.degree. C. to about 160.degree. C. and from about 25 weight percent to about 75 weight percent of at least one polydiene rubber which is cocurable with said syndiotactic 1,2-polybutadiene, sulfur, zinc oxide and at least one pigment or colorant.
摘要翻译：具有白色侧壁的轮胎在美国和加拿大非常受欢迎。具有白色刻字的轮胎也非常受欢迎。本发明公开了一种在其上制备具有装饰贴花的轮胎的方法。通过实践本发明的方法，可以以比使用标准轮胎成型技术更低的成本来建造具有更好的均匀性的轮胎。本发明具体涉及一种制造在其侧壁上具有装饰设计的气动橡胶轮胎的方法，其包括（a）将装饰贴花施加到未硫化轮胎的侧壁上，以及（b）固化轮胎; 其中装饰贴花由约25重量％至约75重量％的间同立构1,2-聚丁二烯组成，间同立构1,2-聚丁二烯的熔点在约70℃至约160℃的范围内，约25重量％至约75重量％的至少一种可与所述间同立构1,2-聚丁二烯，硫，氧化锌和至少一种颜料或着色剂共聚的聚二烯橡胶。

2. 发明授权

US4391737A Catalysts for ring-opening copolymerization of cycloolefins 失效
标题翻译：用于环烯烃开环共聚的催化剂
公开(公告)号：US4391737A
公开(公告)日：1983-07-05
申请号：US272635
申请日：1981-06-11
申请人： Anthony J. Bell
发明人： Anthony J. Bell
IPC分类号： C08F36/00 , C08F4/62 , C08F36/18 , C08G61/00 , C08G61/06 , C08G61/08
CPC分类号： C08G61/08
摘要： A catalyst for the ring-opening copolymerization of a hexachlorocyclopentadiene-1,5-cyclooctadiene adduct and a cycloolefin, other than cyclohexene, having 4 to 12 carbon atoms and containing at least one non-conjugated vinylene double bond. Owing to modification by oxy bidentate-type ligands, the chlorotungsten catalyst system affords a more favorable comonomer reactivity ratio and is thus utilized. The catalyst comprises a compound of (a) the reaction product of tungsten hexachloride and a 1,2- or 1,3- dioxy compound; and a compound (b) having the formula R-AlCl.sub.2 where R is an alkyl group having from 2 to 5 carbon atoms.
摘要翻译：用于六氯环戊二烯-1,5-环辛二烯加成物和除环己烯以外具有4-12个碳原子并含有至少一个非共轭亚乙烯基双键的环烯烃开环共聚的催化剂。由于氧二齿型配体的改性，氯钨催化剂体系提供了更有利的共聚单体的反应活性比例，因而被利用。该催化剂包含（a）六氯化钨与1,2-或1,3-二氧化合物的反应产物的化合物; 和具有式R-AlCl 2的化合物（b），其中R是具有2至5个碳原子的烷基。

3. 发明授权

US5011896A Syndiotactic 1,2-polybutadiene synthesis in an aqueous medium 失效
标题翻译：在水性介质中的间同立构1,2-聚丁二烯合成
公开(公告)号：US5011896A
公开(公告)日：1991-04-30
申请号：US579650
申请日：1990-09-10
申请人： Anthony J. Bell , Eilert A. Ofstead
发明人： Anthony J. Bell , Eilert A. Ofstead
IPC分类号： C08F2/44 , C08F2/16 , C08F2/22 , C08F4/60 , C08F4/70 , C08F4/80 , C08F36/00 , C08F136/06
CPC分类号： C08F136/06
摘要： Pure syndiotactic 1,2-polybutadiene is a thermoplastic resin which has double bonds attached in an alternating fashion to its polymeric backbone. Films, fibers and molded articles can be made utilizing syndiotactic 1,2-polybutadiene. It can also be blended into rubbers and cocured therewith. Syndiotactic 1,2-polybutadiene can be made by solution, emulsion or suspension polymerization. It typically has a melting point which is within the range of about 195.degree. C. to about 215.degree. C. However, it is often desirable for the syndiotactic 1,2-polybutadiene to have a melting point of less than about 195.degree. C. This invention discloses a process for preparing syndiotactic 1,2-polybutadiene having a melting point of less than about 195.degree. C. which comprises: polymerizing 1,3-butadiene monomer in an aqueous medium in the presence of (1) a catalyst composition which is made by reacting (a) at least one cobalt compound (b) at least one organoaluminum compound, and (c) at least one conjugated diene; (2) carbon disulfide; and (3) at least one modifier selected from the group consisting of (a) 4-(alkylamino)benzaldehydes, (b) 4-(dialkylamino)benzaldehydes, (c) 2,4-di-(alkoxy)benzaldehydes, (d) 2,6-di-(alkoxy)benzaldehydes, (e) 2,4,6-tri-(alkoxy)benzaldehydes, and (f) 4-(1-azacycloalkyl)benzaldehydes.

4. 发明授权

US4967818A Tire having decorative applique on sidewall and method for preparing same 失效
标题翻译：具有侧壁装饰贴花的轮胎及其制备方法
公开(公告)号：US4967818A
公开(公告)日：1990-11-06
申请号：US255699
申请日：1988-10-11
申请人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
发明人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
IPC分类号： B29D30/72 , B60C13/04
CPC分类号： B60C13/04 , B29D30/72 , B29D2030/726 , Y10S152/12
摘要： Tires having white sidewalls are very popular in the United States and Canada. Tires having white lettering thereon are also very popular. This invention discloses a process for preparing such tires having decorative appliques thereon. By practicing the process of this invention, tires having better uniformity can be built at lower costs than when standard tire building techniques are utilized. This invention specifically relates to a method of preparing a pneumatic rubber tire having a decorative design on the sidewall thereof which comprises (a) applying the decorative design to the sidewall of an uncured tire and (b) curing the tire; wherein the decorative design is comprised of from about 25 weight percent to about 75 weight percent syndiotactic 1,2-polybutadiene having a melting point which is within the range of about 100.degree. C. to about 160.degree. C. and from about 25 weight percent to about 75 weight perecent of at least one polydiene rubber which is cocurable with said sydiotactic 1,2-polybutadiene, at least one pigment or colorant, sulfur, and zinc oxide.

5. 发明授权

US4435554A Emulsion polymerization process using monobasic alkali phosphate 失效
标题翻译：使用一碱式磷酸盐的乳液聚合方法
公开(公告)号：US4435554A
公开(公告)日：1984-03-06
申请号：US412697
申请日：1982-08-30
申请人： Anthony J. Bell , Leland E. Beyersdorff
发明人： Anthony J. Bell , Leland E. Beyersdorff
IPC分类号： C08F236/12 , C08F4/08
CPC分类号： C08F236/12
摘要： This invention relates to an improved emulsion polymerization process. Specifically, this invention relates to an improved method for producing acrylonitrile-butadiene polymers. The improvement is characterized in that a reaction mixture contains a mono-basic alkali phosphate buffer which results in polymers that are resistant to subsequent Mooney rise.
摘要翻译：本发明涉及一种改进的乳液聚合方法。具体地说，本发明涉及一种生产丙烯腈 - 丁二烯聚合物的改进方法。其改进的特征在于反应混合物含有单碱式碱金属磷酸盐缓冲剂，其导致耐后续门尼上升的聚合物。

6. 发明授权

US4415715A Catalysts for ring-opening copolymerization of cycloolefins 失效
标题翻译：用于环烯烃开环共聚的催化剂
公开(公告)号：US4415715A
公开(公告)日：1983-11-15
申请号：US456677
申请日：1983-01-10
申请人： Anthony J. Bell
发明人： Anthony J. Bell
IPC分类号： C08G61/08 , C08F4/78 , C08F232/08
CPC分类号： C08G61/08
摘要： A catalyst for the ring-opening copolymerization of a hexachlorocyclopentadiene-1,5-cyclooctadiene adduct and a cycloolefin, other than cyclohexene, having 4 to 12 carbon atoms and containing at least one non-conjugated vinylene double bond. Owing to modification by oxy bidentate-type ligands, the chlorotungsten catalyst system affords a more favorable comonomer reactivity ratio and is thus utilized.
摘要翻译：用于六氯环戊二烯-1,5-环辛二烯加成物和除环己烯以外具有4-12个碳原子并含有至少一个非共轭亚乙烯基双键的环烯烃开环共聚的催化剂。由于氧二齿型配体的改性，氯钨催化剂体系提供了更有利的共聚单体的反应活性比例，因而被利用。

7. 发明授权

US5405815A Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber 失效
标题翻译：制备可用于合成异戊二烯 - 丁二烯橡胶的催化剂体系的方法
公开(公告)号：US5405815A
公开(公告)日：1995-04-11
申请号：US77633
申请日：1993-06-17
申请人： Anthony J. Bell , Barry A. Matrana , Adel F. Halasa
发明人： Anthony J. Bell , Barry A. Matrana , Adel F. Halasa
IPC分类号： C08F4/60 , C08F4/58 , C08F236/04 , C08F236/08 , C08F4/52
CPC分类号： C08F236/04
摘要： The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.
摘要翻译：本发明涉及一种用于合成1,3-丁二烯和异戊二烯橡胶状非渐变，无规共聚物的技术。这些橡胶状共聚物表现出用于卡车轮胎的轮胎胎侧橡胶化合物中的优异的性能组合。通过在轮胎侧壁中使用这些异戊二烯 - 丁二烯橡胶，可以在不牺牲滚动阻力的情况下构建具有改善的耐切割生长性的轮胎。这种橡胶也可以用在轮胎胎面胶料中以改善胎面磨损特性并降低滚动阻力而不牺牲牵引特性。本发明更具体地公开了一种用于合成异戊二烯 - 丁二烯橡胶的方法，该方法包括在有机溶剂中，在催化剂体系存在下共聚异戊二烯单体和1,3-丁二烯单体，所述催化剂体系通过以下顺序步骤制备：（1）混合（a）有机氢化铝，（b）选自脂族醇，脂环族醇，脂族硫醇，脂环族硫醇，三烷基硅烷醇和三芳基硅烷醇的成员，和（c）任选的1,3-丁二烯有机溶剂以产生改性的有机铝催化剂组分; （2）将含有周期系III-B族金属的有机金属化合物加入到改性有机铝催化剂组分中以制备含III-B族金属的催化剂组分; 和（3）将含有至少一个不稳定卤素原子的化合物加入到含有III-B族金属的催化剂组分中。

8. 发明授权

US5706402A Blind signal processing system employing information maximization to recover unknown signals through unsupervised minimization of output redundancy 失效
标题翻译：采用信息最大化的盲信号处理系统通过无监督的输出冗余度最小化来恢复未知信号
公开(公告)号：US5706402A
公开(公告)日：1998-01-06
申请号：US346535
申请日：1994-11-29
申请人： Anthony J. Bell
发明人： Anthony J. Bell
IPC分类号： G06K9/62 , G06N3/08 , H04L25/03 , G06F15/31
CPC分类号： G06K9/6242 , G06N3/088 , H04L25/03165 , H03H2021/0034 , H04L2025/03464
摘要： A neural network system and unsupervised learning process for separating unknown source signals from their received mixtures by solving the Independent Components Analysis (ICA) problem. The unsupervised learning procedure solves the general blind signal processing problem by maximizing joint output entropy through gradient ascent to minimize mutual information in the outputs. The neural network system can separate a multiplicity of unknown source signals from measured mixture signals where the mixture characteristics and the original source signals are both unknown. The system can be easily adapted to solve the related blind deconvolution problem that extracts an unknown source signal from the output of an unknown reverberating channel.
摘要翻译：通过解决独立成分分析（ICA）问题，将神经网络系统和无监督学习过程从其接收到的混合物中分离出来。无监督学习过程通过梯度上升最大化联合输出熵来最小化输出中的相互信息来解决通用盲信号处理问题。神经网络系统可以将多个未知源信号与测量的混合信号分离，其中混合特性和原始源信号都是未知的。该系统可以容易地适应于解决从未知混响信道的输出中提取未知源信号的相关盲解卷积问题。

9. 发明授权

US5554410A Delivery of fruit juice, acidulants, and labile components into cooked candy base 失效
标题翻译：将果汁，酸化剂和不稳定成分送入煮熟的糖果基地
公开(公告)号：US5554410A
公开(公告)日：1996-09-10
申请号：US241219
申请日：1994-05-10
申请人： Anthony J. Bell , Daniel J. Streit
发明人： Anthony J. Bell , Daniel J. Streit
IPC分类号： A23G3/02 , A23G3/04 , A23G3/00
CPC分类号： A23G3/04 , A23G3/0205 , A23G3/0215 , A23G3/0226
摘要： The present invention pertains to a method for preparing a hard candy containing from about 1% to about 35% fruit juice, by weight, which comprises the steps of (a) providing a vacuum cooker having a cooker coil, an atmospheric chamber, and a vacuum chamber; (b) forming a sugar syrup having a moisture content from about 0.1% to about 5%, by weight; (c) heating the sugar syrup in the cooker coil to cook the syrup; (d) passing the cooked sugar syrup from the cooker coil to the atmospheric chamber; (e) admixing fruit juice with the cooked sugar syrup in the atmospheric chamber to form a fruit juice-sugar syrup mixture; (f) passing the fruit juice-sugar syrup mixture from the atmospheric chamber to the vacuum chamber to remove excess water; and (g) removing the fruit juice-sugar syrup mixture from the vacuum chamber and forming the fruit juice-sugar mixture into desired shapes of hard candy. This invention also pertains to hard candy containing fruit juice prepared by the inventive method. This invention further pertains to an improved method for making hard candy containing an acidulant or a thermolabile component.
摘要翻译：本发明涉及一种制备硬糖的方法，所述硬糖含有按重量计约1％至约35％的果汁，其包括以下步骤：（a）提供具有炊具盘管，大气室和真空室; （b）形成水分含量为约0.1％至约5％重量的糖浆; （c）加热炊具盘管中的糖浆以制备糖浆; （d）将熟糖浆从炊具盘管送入大气室; （e）在大气室中混合果汁与煮熟的糖浆形成果汁糖浆混合物; （f）将果汁糖浆混合物从大气室送入真空室以除去多余的水; 和（g）从真空室中取出果汁 - 糖浆混合物，并将果汁 - 糖混合物形成所需形状的硬糖。本发明还涉及通过本发明方法制备的含有果汁的硬糖。本发明还涉及一种制备含有酸化剂或不耐热组分的硬糖的改进方法。

10. 发明授权

US5502126A Process for the synthesis of isoprene butadiene rubber 失效
标题翻译：异戊二烯丁二烯橡胶的合成工艺
公开(公告)号：US5502126A
公开(公告)日：1996-03-26
申请号：US330468
申请日：1994-10-28
申请人： Anthony J. Bell , Barry A. Matrana , Adel F. Halasa
发明人： Anthony J. Bell , Barry A. Matrana , Adel F. Halasa
IPC分类号： C08F4/60 , C08F4/58 , C08F236/04 , C08F236/08 , C08F4/52
CPC分类号： C08F236/04
摘要： The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.
摘要翻译：本发明涉及一种用于合成1,3-丁二烯和异戊二烯橡胶状非渐变，无规共聚物的技术。这些橡胶状共聚物表现出用于卡车轮胎的轮胎胎侧橡胶化合物中的优异的性能组合。通过在轮胎侧壁中使用这些异戊二烯 - 丁二烯橡胶，可以在不牺牲滚动阻力的情况下构建具有改善的耐切割生长性的轮胎。这种橡胶也可以用在轮胎胎面胶料中以改善胎面磨损特性并降低滚动阻力而不牺牲牵引特性。本发明更具体地公开了一种用于合成异戊二烯 - 丁二烯橡胶的方法，该方法包括在有机溶剂中，在催化剂体系存在下共聚异戊二烯单体和1,3-丁二烯单体，所述催化剂体系通过以下顺序步骤制备：（1）混合（a）有机氢化铝，（b）选自脂族醇，脂环族醇，脂族硫醇，脂环族硫醇，三烷基硅烷醇和三芳基硅烷醇的成员，和（c）任选的1,3-丁二烯有机溶剂以产生改性的有机铝催化剂组分; （2）将含有周期系III-B族金属的有机金属化合物加入到改性有机铝催化剂组分中以制备含III-B族金属的催化剂组分; 和（3）将含有至少一个不稳定卤素原子的化合物加入到含有III-B族金属的催化剂组分中。

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